Alvito Moura of St Jose de Areal missed two sitters in the 4th and 10th minute as he shot wide.
It was Ratesh Shivolkar who scored the match winner for Navelim Villagers Union in the 52nd minute.
On Sunday, Parish Youth Nuvem blanked Fr Agnel YC Paroda 7-1 to move into the quarter-final.
A four goal blitz by Neves Noronha of Parish Youth Nuvem was the highlight of the day as the striker scored in the 33rd, 40th, 53rd and 70th minute.
While Standly D’Mello, Hayson Velha, Inacio Colaco scored a goal each for the winners. Kanchan Keiro pulled a goal back for Fr Agnel YC Paroda in the 21st minute.
